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Controlled radical polymerization of styrene in the presence of molecular iodine

โœ Scribed by D. I. Shiman; S. V. Kostyuk; L. V. Gaponik; F. N. Kaputskii

Book ID
111463434
Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
222 KB
Volume
83
Category
Article
ISSN
1070-4272

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## Abstract Bulk radical polymerization of styrene in the presence of nitronyl nitroxides (2โ€(4โ€substituted phenyl)โ€4,4,5,5โ€tetramethylโ€4,5โ€dihydroimidazolylโ€1โ€oxyl 3โ€oxide) was studied. All nitronyl nitroxides, like other nitroxyl radicals such as 2,2,6,6โ€tetramethylpiperidine 1โ€oxyl radical (TEMP

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Radical polymerizations of styrene in the presence of C 60 have been conducted at 90ยฐC in benzene using benzoyl peroxide (BPO) as initiator. The behaviors of C 60 are investigated by monitoring BPO concentration, C 60 content, and polymerization time. It is found that C 60 acts like a radical absorb