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Controlled radical copolymerization of styrene and 4-vinylpyridine

✍ Scribed by Michael Baumann; Gudrun Schmidt-Naake

Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
63 KB
Volume
201
Category
Article
ISSN
1022-1352

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📜 SIMILAR VOLUMES

Controlled radical polymerization of 4-v
Controlled radical polymerization of 4-vinylpyridine
✍ Jörg Bohrisch; Ulrich Wendler; Werner Jaeger 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 317 KB

## Abstract 2,2,6,6‐Tetramethylpiperidine‐__N__‐oxyl (TEMPO)‐mediated free radical polymerization of 4‐vinylpyridine is found to proceed in a “controlled” manner. A linear increase of molecular weight along with an increase in conversion occurs at varying temperatures. Polymerization of styrene wit

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## Abstract **Summary:** The block copolymers of styrene and ethyl __α__‐cyanocinnamate were prepared in dioxane and xylene with TEMPO‐capped polystyrene (PSTEMPO) as macroinitiator. The copolymerizations were carried out at 125 °C and 135 °C. The reactivity ratios were determined according to Kele

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Nitroxide-Mediated Controlled/Living Free Radical Copolymerization of Styrene and Divinylbenzene in Aqueous Miniemulsion
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## Abstract **Summary:** The nitroxide‐mediated controlled/living free radical copolymerization of styrene and divinylbenzene using a polystyrene‐TEMPO macroinitiator in aqueous miniemulsion and in bulk have been investigated. The crosslink densities were estimated based on the content of pendant v

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## Abstract Radical polymerization of styrene and mixtures of styrene and 4‐vinylpyridine was performed in the presence of 2,2,6,6‐tetramethylpiperidine‐__N__‐oxyl (TEMPO) producing polymers with controlled molecular weights and molecular weight distributions. The living nature of these polymers wa