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Controlled Polymerization of Methacrylates to High Molecular Weight Polymers Using Oxidatively Activated Group Transfer Polymerization Initiators

✍ Scribed by Zhang, Yuetao; Chen, Eugene Y.-X.


Book ID
127234285
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
191 KB
Volume
41
Category
Article
ISSN
0024-9297

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## Abstract The first RAFT mediated polymerization of methyl methacrylate initiated by diradicals derived from Bergman cyclization was performed employing 3,4‐benzocyclodec‐3‐ene‐1,5‐diyne (BCDY) as diradical source and cyanoisopropyldithiobenzoate (CPDB) as RAFT agent. The polymerization was condu