## Abstract Four novel Schiff‐type chitosan (CTS)‐crown ethers were synthesized through a reaction between NH~2~ in CTS or crosslinked chitosan (CCTS) and CHO in 4′‐formylbenzo‐crown ethers, and four secondary‐amino‐type CTS‐crown ethers were prepared through the reduced reaction of NaBH~4~, resp
Controlled Chemical Modifications of Chitosan. Characterization and Investigation of Original Properties
✍ Scribed by Rachel Auzély; Marguerite Rinaudo
- Publisher
- John Wiley and Sons
- Year
- 2003
- Tongue
- English
- Weight
- 113 KB
- Volume
- 3
- Category
- Article
- ISSN
- 1616-5187
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✦ Synopsis
Abstract
The main techniques developed to characterize chitosan are recalled. The interaction of chitosan with oppositely charged surfactants was investigated giving very important surface activity effects. A few chemical modifications are described and the new properties obtained are mentioned: alkylation gives amphiphilic polymers having interesting thickening behavior; grafting cyclodextrin (chit‐CD) gives a polymer able to include hydrophobic molecules; grafting adamantane gives an amphiphilic polymer able to specifically interact with chit‐CD forming a temporary network with gel‐like behavior.
The viscosities of adamantane‐chitosan, cyclodextrin‐chitosan, and unmodified chitosan solutions studied here.
magnified imageThe viscosities of adamantane‐chitosan, cyclodextrin‐chitosan, and unmodified chitosan solutions studied here.
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