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Controlled Cationic Ring-Opening Polymerization of a Six-Membered Cyclic Thiourethane

✍ Scribed by Nagai, Daisuke; Sato, Masato; Ochiai, Bungo; Endo, Takeshi


Book ID
127391646
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
51 KB
Volume
37
Category
Article
ISSN
0024-9297

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✍ Masatoshi Miyamoto; Keigo Aoi; Takeo Saegusa πŸ“‚ Article πŸ“… 1997 πŸ› John Wiley and Sons 🌐 English βš– 277 KB πŸ‘ 2 views

The cationic ring-opening polymerization of six-membered cyclic pseudoureas, 2-(1-pyrrolidinyl)-( 2a) and 2-morpholino-5,6-dihydro-4H-1,3-oxazine ( 2b), was examined, which proceeded in two different ways, depending on the nature of initiator. The polymerization of 2 with methyl p-toluenesulfonate o