Controlled Cationic Polymerization of Hexamethylcyclotrisiloxane †
✍ Scribed by Toskas, G.; Moreau, M.; Masure, M.; Sigwalt, P.
- Book ID
- 125507702
- Publisher
- American Chemical Society
- Year
- 2001
- Tongue
- English
- Weight
- 90 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0024-9297
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📜 SIMILAR VOLUMES
## Abstract The solid‐state polymerization of hexamethylcyclotrisiloxane has been shown, by means of specific ion scavengers, to proceed by a cationic process. The reaction occurs at the crystal surface rather than within the lattice and exhibits a polymerization rate which is inversely proportiona
## Abstract Silyl trifluoromethanesulfonates are inactive for the polymerization of cyclosiloxanes in the complete absence of trifluoromethanesulfonic (triflic) acid, but polymerization occurs in its presence. Using a triflic ester as tagged silyl triflate (benzyldimethylsilyl triflate) the degree