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Controlled Anionic Polymerization of Methacrylonitrile with Diphenylmethylpotassium in the Presence of Triethylborane

✍ Scribed by Ishizone, Takashi; Yanase, Eriko; Matsushita, Takehiro; Nakahama, Seiichi

Book ID
126035687
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
29 KB
Volume
34
Category
Article
ISSN
0024-9297

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## Abstract The polymerization of butadiene by lithium‐based initiators in aliphatic hydrocarbon solvents in the presence of dipiperidinoethane gives a highly 1,2 structure. This system was studied to determine the factors that govern the structure. The effect of this complexing agent on the kineti