✦ LIBER ✦
Controlled Alternating Copolymerization of (Meth)acrylates and Vinyl Ethers by Using Organoheteroatom-Mediated Living Radical Polymerization
✍ Scribed by Eri Mishima; Shigeru Yamago
- Publisher
- John Wiley and Sons
- Year
- 2011
- Tongue
- English
- Weight
- 325 KB
- Volume
- 32
- Category
- Article
- ISSN
- 1022-1336
No coin nor oath required. For personal study only.
✦ Synopsis
Abstract
Alternating copolymers comprised of (meth)acrylates and vinyl ethers with controlled molecular weights and polydispersities were synthesized for the first time by living radical polymerization using organotellurium, stibine, and bismuthine chain transfer agents. Combining living alternating copolymerization and living radical or living cationic polymerization afforded hitherto unavailable block copolymers with controlled macromolecular structures. magnified image