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Controllable synthesis, structures of amidecrownophane-type macrocycles and their binding ability toward anions

✍ Scribed by Wei-tao Gong; Junichi Harigae; Joobeom Seo; Shim Sung Lee; Kazuhisa Hiratani

Publisher
Elsevier Science
Year
2008
Tongue
French
Weight
446 KB
Volume
49
Category
Article
ISSN
0040-4039

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✦ Synopsis

Amidecrownophane-type macrocycles with different number of hydroxy groups were prepared in quantitative yields by control of the conditions of thermal reaction with the aim to examine the role of hydroxy groups in anion recognition. It was proved that the hydroxy group played a critical role in anion binding for this type of macrocycles and the anion binding affinity could be tuned by different number of hydroxy groups. Further exploration clarified the presence of intramolecular hydrogen-bonding and exhibited the major effect on their anion binding potential.

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