A single crystal X-ray analysis of [Ni 2 L1](ClO 4 ) 2 β’ MeCN β’ 1/ thiocyanate ions, forming [Ni 2 L1(NCS) 2 ] 4 and [Ni 2 L2(NCS) 2 ] 5 respectively, whereas 3 does not. Single crystal X-ray 4 H 2 O, 1a [formed directly from a mixture of nickel(II) template ions, 2,6-diformyl-4-methyl-thiophenolate
Control of the electro-oxidation of macrocyclic complexes of Co(II) by axial coordination
β Scribed by Chan Kang; Fred C. Anson
- Publisher
- Elsevier
- Year
- 1996
- Tongue
- English
- Weight
- 332 KB
- Volume
- 407
- Category
- Article
- ISSN
- 1572-6657
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π SIMILAR VOLUMES
The nickel(II) complex 3 containing a 14-membered macrocyclic triphosphine phosphinate ligand is obtained by regioselective oxidation of the crown phosphine nickel(II) complex 2c with molecular oxygen. The X-ray structure of 3β’H 2 O (space group P2 1 /c) has been determined. Oxidation of the macrocy
## Abstract The coordination polymer {[Ni(C~20~H~32~N~8~)]~2~[TCM]}Β·5DMFΒ·8H~2~O (1) has been assembled from a Ni^II^ macrocyclic complex that contains two pyridyl pendant arms, [Ni(C~20~H~32~N~8~)](ClO~4~)~2~, and sodium tetrakis[4β(carboxyphenyl)oxamethyl]methane (Na~4~TCM) in DMF/water. The Xβray