Control of micropore diffusivities of molecular sieving carbon by deposition of hydrocarbons
โ Scribed by Kazuyuki Chihara; Motoyuki Suzuki
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 390 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0008-6223
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โฆ Synopsis
Adsorption of ethylbenzene and styrene at 1504WC followed by heat treatment at 400ยฐC was tried for controlling diffusivities in micropores of Molecular Sieving Carbon. The amount of carbon deposited after heat treatment is a function of adsorption temperature. Diffusivities of oxygen and nitrogen were measured using the chromatographic method and found to decrease sharply with the small increase of the amount of carbon deposited. The ratio of 02/N2 diffusivities, however, was little affected by this treatment.
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Modification ofthe pore structure of microporous carbons by depositing carbon from pyrolysis of CJH6 between 973-I I23 K was investigated in regard to development of molecular sieving properties for separation of O2 and Ar. Excellent adsorption kinetics and selectivity for separation of O2 and Ar we
Experimental saturation (adsorption) and regeneration (desorption) breakthrough curves are reported for a molecular sieve adsorption column operated isothermally under conditions of micropore diffusion control. For systems with a linear equilibrium isotherm, column performance may be adequately pred
A process is described for preparing a carbon molecular sieve that is suitable for the kinetic separation of gases, such as oxygen from nitrogen. 'The process involves modifying a carbon support, having a majority of micropores with an effective pore size of about 4.5 to 20 A, using a two-step proce
The effect of thermal treatment on the porosity of microporous carbons, of pore structure ranging between that of a carbon molecular sieve (CMS) and an activated carbon (AC), was investigated by adsorption and diffusion of 0, and Ar. Sieving behavior was improved in the case of carbons containing mo
Modification of the pore size of several types of carbon adsorbents by chemical vapour deposition of carbon from benzene at 1000 K was examined. The carbons included commercial molecular sieve carbon (MSC), pitch based active carbon fiber (ACF), super and commercial active carbon (S-AC, AC). Greatly