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Control of Liquid Crystallinity of Diazadibenzoperylene Dyes by Covalent and Hydrogen-Bonded Attachment of Mesogens

✍ Scribed by Armin Sautter; Christoph Thalacker; Frank Würthner


Publisher
John Wiley and Sons
Year
2001
Tongue
English
Weight
453 KB
Volume
113
Category
Article
ISSN
0044-8249

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✦ Synopsis


Dedicated to Dr. G¸nther Seybold on the occasion of his 60th birthday

Functional liquid crystals (LCs) with intrinsic luminescence properties are of great interest in the development of new organic materials, such as anisotropic light emitters, organic lasers, photoconductors, and in LC display technology. [1±3] In contrast to dissolving a fluorescent dye in a LC matrix, fluorescent LCs are thought not only to overcome miscibility and stability problems but also to exhibit novel enhanced optoelectronic properties. To date, only a few examples have been reported such as triphenylenes, [3a±d] benzopyrenes, [3e] hexacatenar compounds, [1a] and perylenes, but the field is IR (KBr):


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Supramolecular liquid-crystalline polymeric complexes based on a backbone that contains vinyl pyridine units and azobenzene or biphenyl derivatives that posses alkyl chains terminated by carboxylic acid have been obtained by the formation of intermolecular hydrogen bonds between the carboxylic acid