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Control of intramolecular electron transfer by protonation: oligomers of ruthenium porphyrins bridged by 4,4'-azopyridine

โœ Scribed by Marvaud, Valerie; Launay, Jean Pierre


Book ID
115530308
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
788 KB
Volume
32
Category
Article
ISSN
0020-1669

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Iodo-(5,10,15,20-tetrakis(1,2,3,4,5,6,7,8-octahydro-1,4:5,8-dimethanoanthracen-9-yl)porphyrinatorhodium(III), designated as [Rh(P\*)(I)], was prepared and its catalytic activity in the asymmetric cyclopropanation of alkenes with ethyl diazoacetate (EDA) was examined. High catalyst turnovers (TON >10