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Control of chemoselectivity in the rhodium(II)-catalyzed alkyne insertion reaction of .alpha.-diazo ketones

✍ Scribed by Padwa, Albert; Austin, David J.; Xu, Simon L.

Book ID
120361634
Publisher
American Chemical Society
Year
1992
Tongue
English
Weight
234 KB
Volume
57
Category
Article
ISSN
0022-3263

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Fluorinated Diazo Diketones in Rhodium(I
Fluorinated Diazo Diketones in Rhodium(II)-Catalyzed Reactions with Sultams: Chemoselective O-Functionalization of Amide Carbonyl Groups
✍ Valeria M. Zakharova; Bärbel Schulze; Ludmila L. Rodina; Joachim Sieler; Valerij 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 German ⚖ 321 KB

## Abstract Rhodium(II)‐catalyzed decomposition of fluorinated diazo diketones in the presence of isothiazole‐3(2__H__)‐one 1,1‐dioxides offers a chemoselective and useful tool for __O__‐functionalization of their CO groups by interaction with transient fluorine‐containing Rh^II^‐diketocarbenoids.