Control of Chemo- and Regioselectivity in the Palladium-Catalyzed Telomerization of Butadiene with Methanol − Catalysis and Mechanism
✍ Scribed by Frank Vollmüller; Jochen Krause; Susanne Klein; Wolfgang Mägerlein; Matthias Beller
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 305 KB
- Volume
- 2000
- Category
- Article
- ISSN
- 1434-1948
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📜 SIMILAR VOLUMES
The structure and reactivity of various bis-allylpalladium complexes occurring as catalytic intermediates in important synthetic transformations have been studied by applying density functional theory at the B3PW91(DZ P) level. It was found that h 1 ,h 3 coordinated bis-allylpalladium complexes are
The stoichiometry
## Abstract magnified image Described herein is the development of a palladium(II)‐catalyzed two‐ or three‐component reaction of 2‐(1‐alkynyl)‐2‐alken‐1‐ones with nucleophiles and allylic chlorides. Various types of nucleophiles such as __O‐__, __N‐__, __C__‐based nucleophiles and olefin‐tethered