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Control aromaticity in the thermal decomposition of 2,5-dihydrofuran, 2,5-dihydrothiophene and 3-pyrroline: a kinetic and thermodynamic study via DFT

✍ Scribed by Abolfazl Shiroudi; Ehsan Zahedi; Reza Zabihi


Book ID
106513196
Publisher
Springer-Verlag
Year
2010
Tongue
English
Weight
351 KB
Volume
102
Category
Article
ISSN
1878-5190

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Kinetic and thermodynamic control in the
✍ Michelangelo Gruttadauria; Renato Noto πŸ“‚ Article πŸ“… 2001 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 38 KB

## Abstract The stereoselective rearrangement of tetrahydrofuran or tetrahydropyran rings having a phenylsulfanyl group in an __exo__ position, __via__ the intermediate thiiranium ions, is reported. The 5‐ or 6‐__exo__‐tet cyclization of hydroxy sulfides gave the kinetic products while the 6‐__endo