Control and Quenching of Electroosmotic Flow with End-Grafted Polymer Chains
✍ Scribed by Tessier, Frédéric; Slater, Gary W.
- Book ID
- 123618747
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 178 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0024-9297
No coin nor oath required. For personal study only.
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## Abstract We report molecular dynamics simulations on bottle‐brush polyelectrolytes end‐grafted to a planar surface. For each bottle‐brush polyelectrolyte, flexible charged side chains are anchored to one neutral main chain. The effects of the counterion valence and the grafting density on the de
## Abstract In aqueous capillary electrophoresis the electroosmotic flow (EOF) can be strongly suppressed or eliminated by coating the capillary surface silanols either by buffer additive adsorption or chemical modification. Hydrophilic coatings, __e.g.,__ polyvinyl alcohol (PVA) proved to be most