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Contribution to the chemistry of perfluoroallyl chloride and some other chlorofluoropropenes

✍ Scribed by O. Paleta; J. Kvíčala; V. Dědek

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
48 KB
Volume
29
Category
Article
ISSN
0022-1139

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✦ Synopsis

The synthesis of these s.ubstances is based on the ionic addition reaction of Freon 11 with fluorinated ethylenes. This reaction yields halogenopropanes, which, by means of fluorination, dehalogenation and photochemical reduction, were converted to the following f>uoropropenes: C1CF2-CF=CP2, CF3-CF=CClF, CF3-CF=CC$ C1CF2-CF=CClF, C1CF2-CP=CC12, and CF3-CF=CHCl . The chemical properties of the fluoropropenes were studied on their reactions with KF, with CH30H under basic catalysis, and under the conditions of a photochemically initiated re-

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