An analysis of the intermolecular field of solid nitrogen and carbon monoxide is based on experimental values of the sublimation energies of the crystals, extrapolated to 0ยฐK. The intermolecular field is assumed to consist of a Lennard-Jones part, a part due to orientation and induction effects of t
โฆ LIBER โฆ
Contribution to the analysis of molecular interactions in compressed nitrogen and carbon monoxide: Part III. Quadrupole orientation and induction effects at high temperatures
โ Scribed by L. Jansen; A. Michels; J.M. Lupton
- Publisher
- Elsevier Science
- Year
- 1954
- Weight
- 290 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0031-8914
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โฆ Synopsis
With the values of the quadrupole moments of nitrogen and carbon monoxide, as determined in a previous publication, the analysis of molecular interaction at high densities is concluded. Neither the quadrupole orientation, nor quadrupole induction or dipole-quadrupole orientation energies contribute significantly to the internal energy of these gases at high temperatures. The calculations are followed by a summary of the main results of this analysis.
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