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Contribution of the ligand to the electroreduction of CO 2 catalyzed by a cobalt(II) macrocyclic complex

✍ Scribed by Isaacs, Mauricio; Canales, Juan C.; Riquelme, Andrea; Lucero, Mauricio; Aguirre, María J.; Costamagna, Juan


Book ID
120526386
Publisher
Taylor and Francis Group
Year
2003
Tongue
English
Weight
403 KB
Volume
56
Category
Article
ISSN
0095-8972

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Mechanism of electrode poisoning in the reduction of CO2 catalyzed by [Ni(CRH)12+ and [Ni(cyclam)12+ is studied by cyclic and stripping dc voltammetry. In both cases the product of CO2 reduction is CO, which undergoes further reaction with the Ni(1) form of the catalyst. Comparison of the process in