✦ LIBER ✦
Contribution of the lattice energy to the stability of aliovalent iron species formed after 57Co decay in CoX2 (X = F, Cl, Br, Oh)
✍ Scribed by A. Cruset; J. M. Friedt
- Book ID
- 104542367
- Publisher
- John Wiley and Sons
- Year
- 1971
- Tongue
- English
- Weight
- 297 KB
- Volume
- 44
- Category
- Article
- ISSN
- 0370-1972
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✦ Synopsis
Abstract
Mössbauer emission spectra of ^57^Co in β‐Co(OH)~2~ and CoBr~2~ are reported. The proportion of ferric ions stabilized after ^57^Co electron capture increases with increasing lattice energy along the series of cobaltous compounds; a thermodynamical model is suggested to explain the stability of aliovalent ions after ^57^Co EC in cobalt compounds with simple ligands.