Poursuivant l'etude consacree i l'electrochimie des thiols et disulfures [l-,-3 J nous nous sommes inikesses B l'acide thiobarbiturique et a son derive le pentothal sodique. Ces deux composes sont d'une importance pharmacologique considerable ayant servi de noyau de base & un grand nombre de produit
Contribution a l'électrochimie des thiols et disulfures : Partie I. Cystéine et cystine
✍ Scribed by C.A. Mairesse-Ducarmois; G.J. Patriarche; J.L. Vandenbalck
- Book ID
- 108305264
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 631 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0003-2670
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## Abstract In order to examine the importance of Sommelet and Stevens rearrangement versus β‐elimination, the reaction of sodium amide in liquid ammonia on 1‐methyl‐benzylpiperidinium iodide was examined and found to give three isomeric tertiary bases: two of them resulting from a Sommelet rearran
Reaction of 2-methyl-2-benzyl-l,2,3,4-tetrahydroisoquinolinium iodide with sodium amide in liquid ammonia yields 76% l-orthotolyl-2-methy1-1,2,3,4-tetrahydroisoquinoline resulting from a Sommelet-Hauser rearrangement. In the same conditions, 2,2-dimethyl-1,2,3,4-tetrahydroisoquinolinium iodide yield