𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Continuum-source atomic absorption spectrometry — new lamps for old?

✍ Scribed by John Marshall; Barbara J. Ottaway; John M. Ottaway; David Littlejohn


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
935 KB
Volume
180
Category
Article
ISSN
0003-2670

No coin nor oath required. For personal study only.

✦ Synopsis


A short review is presented on the development of continuum-source atomic absorption spectrometry (CSAAS) . The current status of the technique is assessed and the application of microcomputer controlled single channel CSAAS to the analysis of standard reference materials is described .

The field of atomic absorption spectrometry (AAS) has grown enormously in the last 25-30 years . The pioneering work of Walsh [1] and Alkemade and Milatz [2] has profoundly affected the way in which trace element determinations are carried out in laboratories throughout the world . Although there have been significant developments in AAS instrumentation in the intervening years, the principle of the measurement has remained essentially the same since its inception . The use of a narrow-line spectral light source for AAS measurement was hailed, rightly, as a major breakthrough in the development of analytical atomic spectrometry . The classic exposition of the technique by Walsh [1] has been reiterated in countless papers and textbooks . It is now almost axiomatic that a narrow-line light source, such as a hollow-cathode lamp, is required in order to make sensitive atomic absorption measurements . Yet the future development of the technique may well depend on questioning this rationale, since it imposes severe restrictions on the design of instrumentation for AAS .

HISTORICAL PERSPECTIVES

In offering at alternative basis for atomic absorption measurement, it is pertinent to consider the historical development of the subject . Lockyer [3] described an experimental system for studying absorption spectra as long ago as 1875 . A pictorial representation of the apparatus used, taken from a text published around that time [4] is shown in Fig . 1 . The experimental **Present address : I.C.I. p.l.c., Petrochemicals and Plastics Division,


📜 SIMILAR VOLUMES


A new flow injection single-standard cal
✍ Fang Zhaolun; Xu Shukun; Bai Xuesheng 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 583 KB

A flow injection (FI) calibration method for flame atomic absorption spectrometry was developed which involved microsampling of a single standard using computer controlled stepper-motor driven peristaltic pumps. The theoretical basis for the method is given, demonstrating the feasibility of utilizin

A new continuous hydride generator for t
✍ Xiao-Chun Le; William R. Cullen; Kenneth J. Reimer; Ian D. Brindle 📂 Article 📅 1992 🏛 Elsevier Science 🌐 English ⚖ 814 KB

## Ahstraet A new contmuous hydnde generator IS described Its charactenstlcs are compared with a conventional hydnde generator for the determmatton of arsenic, antimony and tm by usmg flame atonuc absorption spectrometly Thus sunple hydride generator combmes hydnde production and gas-bqmd separati