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Continuous-Flow CH Borylation of Arene Derivatives

✍ Scribed by Tsuyoshi Tagata; Mayumi Nishida; Atsushi Nishida

Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
271 KB
Volume
352
Category
Article
ISSN
1615-4150

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✦ Synopsis

Abstract

A new continuous‐flow system for CH borylation has been developed. An insoluble catalyst prepared from chloro(1,5‐cyclooctadien)iridium(I) dimer and 2,2′‐bipyridine‐4,4′‐dicarboxylic acid in the presence of bis(pinacolato)diboron exhibited high reactivity under continuous‐flow processing without the loss of expensive iridium metal.

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