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Contact reduction of copper(II) on aluminum in ammonia solutions

✍ Scribed by A. F. Dresvyannikov; I. O. Grigor’eva

Book ID: 111461440
Publisher: SP MAIK Nauka/Interperiodica
Year: 2006
Tongue: English
Weight: 139 KB
Volume: 79
Category: Article
ISSN: 1070-4272
DOI: 10.1134/s1070427206050119

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## Abstract To understand the chemistry of Cu(II)–NH~3~–S(IV)–O~2~ system, the kinetics of the oxidation of sulfur(IV) catalyzed by amminecopper(II) complexes has been studied in the ammonia‐buffered solutions. Sulfur(IV) is oxidized to sulfate. The complexes, Cu(NH~3~)^2+^, Cu(NH~3~)~2~^2+^, and C