Contact angles; wetting and de-wetting of mercury: Part III. Contact angles on mercury
β Scribed by C. A. Smolders
- Publisher
- Elsevier Science
- Year
- 2010
- Tongue
- English
- Weight
- 991 KB
- Volume
- 80
- Category
- Article
- ISSN
- 0165-0513
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β¦ Synopsis
Abstract
In the system mercury/aqueous Naβdecane sulfonate/hydrogen contact angles are obtained by calculation from the three interfacial tensions, and by direct measurement.
Electrocapillary measurements are described, by which the influence of the surface charge (surface potential) on the adsorption of Nadecane sulfonate at the mercury/solution interface is studied.
Using the sessile drop method, equilibrium surface tension data are obtained for all three interfaces, and for different values of the surface potential of the mercury.
Calculated and measured contact angles are in good agreement over a range of concentrations of Naβdecane sulfonate.
The problem of the thickness of the solution layer at the mercury/gas interface is discussed.
π SIMILAR VOLUMES
## Abstract A survey is given of the existing methods for measuring the surface tension from the geometry of sessile drops. These methods, which generally consist of the measurement of simple drop dimensions, are insufficiently accurate for use with adsorption studies. A new procedure is described