Construction of Titanasiloxanes by Incorporation of Silanols to the Metal Oxide Model [{Ti(η5-C5Me5)(μ-O)}3(μ3-CR)]: DFT Elucidation of the Reaction Mechanism

Synthetic and Theoretical Study of the I

Synthetic and Theoretical Study of the Incorporation of Metal Halides in [{Ti(η5-C5Me5)(μ-NH)}3(μ3-N)]

✍ María García-Castro; José Gracia; Avelino Martín; Miguel Mena; Josep-M. Poblet; 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 232 KB 👁 1 views

## Abstract The capacity of the imido‐nitrido organometallic ligand [{Ti(η^5^‐C~5~Me~5~)(μ‐NH)}~3~(μ~3~‐N)] (1) to entrap main group metal halides MX~__n__~ has been investigated. Treatment of 1 with metal halides in toluene or dichloromethane afforded several soluble adducts [MX~__n__~(L)] (L=1) i