Metal ion specific template ligand sites were developed by physically immobilizing dithizone molecules oriented according to a particular complex geometry in various polymeric films. Four polymeric systems, polystyrene, poly ( methyl methacrylate) , poly ( vinyl chloride) , and polycarbonate, were u
โฆ LIBER โฆ
Construction of template polymeric ligand with 8-hydroxy quinoline
โ Scribed by A. Ray; S. N. Gupta
- Book ID
- 101251279
- Publisher
- John Wiley and Sons
- Year
- 1998
- Tongue
- English
- Weight
- 180 KB
- Volume
- 67
- Category
- Article
- ISSN
- 0021-8995
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โฆ Synopsis
8-Hydroxy quinoline was coupled with half diazotized p-pheylene diamine. Complexes of Cu 2/ , Ni 2/ , Zn 2/ , and Co 2/ were prepared with the resulting dye-ligand. The complexes were then covalently bound into a crosslinked polymer matrix based on styrene-acrylamide copolymer through the ligand moiety. After removal of the metal ions from the polymer matrix, the metal ion absorption capacities of the polymer bound ligands were measured. The procedure could induce some specificities with template effect.
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