Construction and Properties of Hydrophobic Association Hydrogels with High Mechanical Strength and Reforming Capability
✍ Scribed by Guoqing Jiang; Chang Liu; Xiaoli Liu; Guohui Zhang; Meng Yang; Fengqi Liu
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 418 KB
- Volume
- 294
- Category
- Article
- ISSN
- 1438-7492
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✦ Synopsis
Abstract
Hydrophobic association hydrogels (HA‐gels) with almost ideal properties were successfully prepared by micellar copolymerization, and the associated micelles acted as physical cross‐linking points in the network of HA‐gels. HA‐gels exhibit exceptional mechanical properties and transparency. However, the most striking properties are that HA‐gels possess the capability of self‐healing and remolding, which is mainly due to the dissociation and re‐association process of the associated micelles. Dried‐gels, which were prepared by stretching HA‐gels to a certain elongation for a period of time in the air, can be used as shrinkable or thermal sensitivity materials. HA‐gels have a broad selectivity for components, so we have synthesized HA‐gels with variously available properties by changing a corresponding component: thermoresponsive HA‐gels, nanosphere‐composite HA‐gels, and fluorescent HA‐gels. Therefore, we are sure that HA‐gels will be widely used in various fields, such as biology, medication, sensors, optics, and oil exploitation.
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