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Constrained Geometry Tetramethylcyclopentadienyl-phenoxytitanium Dichlorides: Template Synthesis, Structures, and Catalytic Properties for Ethylene Polymerization

✍ Scribed by Zhang, Yuetao; Mu, Ying; Lü, Chunsheng; Li, Guanghua; Xu, Jiansheng; Zhang, Yanrong; Zhu, Dongsheng; Feng, Shouhua

Book ID
126892975
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
127 KB
Volume
23
Category
Article
ISSN
0276-7333

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Half-Titanocence Anilide Complexes Cp′TiCl2[N(2,6-R12C6H3)R2]: Synthesis, Structures and Catalytic Properties for Ethylene Polymerization and Copolymerization with 1-Hexene
✍ Kefeng Liu; Qiaolin Wu; Wei Gao; Ying Mu; Ling Ye 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 516 KB

## Abstract A number of new half‐sandwich titanium(IV) complexes of the type [Cp′TiCl~2~{N(2,6‐R^1^~2~C~6~H~3~)R^2^}] [R^1^ = __i__Pr (1, 2, 4), Me (3, 5); R^2^ = Me (1, 3, 4, 5), Bn (2); Cp′ = Cp (1, 2, 3), Cp\* (4, 5)] have been synthesized by the reaction of [Cp′TiCl~3~] with the lithium salts o