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Constitutional effects on the competing syn- and anti-pathways in bimolecular elimination: Comments on the brown-ingold controversy

✍ Scribed by M. Pánková; J. Závada

Publisher: Elsevier Science
Year: 1973
Tongue: French
Weight: 327 KB
Volume: 14
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)87604-8

No coin nor oath required. For personal study only.

✦ Synopsis

The question whether steric3 or polar 4 effects control the course of E2 reactions in open-chain systems was discussed ardently during past decades and opposing views (Brown-Ingold controversy) remained irreconciled5. Our discovery that E2 reactions do not always proceed homogeneously by the anti-mechanism, as it was originally anti-NO. 24

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