✦ LIBER ✦

Constant time interval method for analysis of reaction rate data

✍ Scribed by Norman E. Shank

Publisher: John Wiley and Sons
Year: 1973
Tongue: English
Weight: 240 KB
Volume: 5
Category: Article
ISSN: 0538-8066
DOI: 10.1002/kin.550050408

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✦ Synopsis

Abstract

In the study of chemical kinetics, many integrated reaction rate equations have the form In [f(A) + a] = bt + c, where a, b, and c are constants and f(A) is some function of the concentration of a reactant (or product) which can be calculated from the data. The left‐hand side of this equation cannot be graphed versus time if the constant a is unknown. However, it is shown that f(A2) varies linearly with f(A~1~) if A~2~ is the concentration of reactant measured at a constant time interval later than A~1~. The constants a and b can be determined from the linear graph. A number of specific examples are considered.

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