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Conservation of the Nuclear Spin Modification of CH4 in the Cooling Process by Supersonic Jet Expansion

โœ Scribed by M. Hepp; G. Winnewisser; K.M.T. Yamada


Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
138 KB
Volume
164
Category
Article
ISSN
0022-2852

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The propargyl radical (CH,C-CH ) was produced in a pulsed supersonic jet expansion by the 193 nm excimer laser photolysis of propargyl chloride, and detected by the method of time-resolved infrared diode laser spectroscopy. A rotational temperature of 16 & 4 K was obtained in an experiment in which