Consequence of the Metal-Atom Clustering on the Magnetic Properties in Vanadium Sulfide V5S8

✍ Scribed by H.-J. Koo; D.-K. Seo; M.-H. Whangbo

• Publisher: Elsevier Science
• Year: 2001
• Tongue: English
• Weight: 263 KB
• Volume: 160
• Category: Article
• ISSN: 0022-4596
• DOI: 10.1006/jssc.2001.9260

✦ Synopsis

On the basis of qualitative bonding considerations and tightbinding electronic band structure calculations, we examined how the unequal spin moment distribution is related to the metalatom clustering in V 5 S 8 and why V 5 S 8 exhibits both localized and itinerant magnetic properties.