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Consecutive chemical reactions in an annular reactor with non-newtonian flow

✍ Scribed by Lin, Sheng Hsiung


Publisher
Springer
Year
1974
Tongue
English
Weight
449 KB
Volume
30
Category
Article
ISSN
0003-6994

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✦ Synopsis


The purpose of this paper is to analyze tile homogeneous consecutive chemical reactions carried out in an annular reactor with non-Newtonian laminar flow. The fluids are assumed to be characterized by a Ostwald-de Waele (powerlaw) model and the reaction kinetics is considered of general order. Effects of flow pseudoplasticity, dimensionless reaction rate constants, order of reaction kinetics and ratio of inner to outer radii of reactor on the reactor perforinances are examined in detail.

Nomenclature

ca CB CA0 C1 C2 DA DB k. kn Ki K~ K n B r ri concentration of reactant A, g.mole/cm 3 concentration of reactant B, g.mole/cm 3 inlet concentration of reactant A, g.mole/cm 3 dimensionless concentration of A, cA/cAo dimensionless concentration of B, eB/c.o dimensionless bulk concentration of A dimensionless bulk concentration of B molecular diffusivity of A, cm2/sec molecular diffusivity of 13, cm2/sec first reaction rate constant, (g.mole/cm3)l-m/sec second reaction rate constant, (g.mole/cma)l-n/sec dimensionless first reaction rate constant, kAr~cnd~l/Da dimensionless second reaction rate constant, kBr~c~l/DB apparent viscosity, dyne(sec)m/cm 2 order of reaction kinetics order of reaction kinetics pressure, dyne/cm~ radial coordinate, cm radius of inner tube, cm


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