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CO−NO and CO−O 2 Interactions on Cu(100) between 25 and 200 K Studied with Infrared Reflection Absorption Spectroscopy

✍ Scribed by Kim, C. M.; Yi, C.-W.; Goodman, D. W.

Book ID
126209993
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
95 KB
Volume
109
Category
Article
ISSN
0022-3654

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We present the results of the in situ infrared study of the behavior of NO with CO on Pt(100) carried out in a continuous Ñow reactor at 470 K and 500 K. The frequency of the solitary IR band observed at 470 K during adsorption of nitric oxide shifted by 68-73 cm-1 when we used 15N18O instead of NO.