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Connecting [4Fe-4S] Clusters and Hemes - Towards Modeling the Active Site of Sulfite Reductase

✍ Scribed by Gerlach, Deidra L.; Coucouvanis, Dimitri; Lehnert, Nicolai


Book ID
120595729
Publisher
John Wiley and Sons
Year
2013
Tongue
English
Weight
954 KB
Volume
2013
Category
Article
ISSN
1434-1948

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Induced paramagnetism and hyperfine inte
✍ Moisey I. Belinsky πŸ“‚ Article πŸ“… 1996 πŸ› Elsevier Science 🌐 English βš– 639 KB

The spin-coupling model of the {[Fe4S4]-siroheme} center of the active site of sulfite reductase is developed. The tetmmer-siroheme coupling 2JthS j -s h results in the induced paramagnetism of individual ions of the Fe/S tetramer which = ~ \_\_ 33/j .j. provides non-zero effective hyperfine consta