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Conjugative stabilization in organosilicon reactive intermediates

โœ Scribed by Marie Heaton; Pamela Z. Rogers; Dennis D. Davis


Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
508 KB
Volume
85
Category
Article
ISSN
0037-9646

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๐Ÿ“œ SIMILAR VOLUMES


Studies on organosilicon reactive interm
โœ Shi-Hui Wu; Hu Qian; Ge Wu; Nan Jiang ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 575 KB

Both 2-phenyl-2-furylhexamethyltrisilane (1) and 2phenyl-2-thienylhexamethyltrisilane (2) were synthesized by conventional organometallic reactions. The photolysis of 1 in the presence of 2,3-dimethyl-1,3butadiene led to normal silylene-olefin addition and silylene C-H insertion reactions. However,

Studies on organosilicon reactive interm
โœ Shihui Wu; Yumei Luo; Fei Liu; Shiming Chen ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 511 KB

The synthesis of di(a-thieny1)hexamethyltrisilane (1) is described. In the photolysis of 1 with cyclohexene and methanol, an apparent radical reaction occurred. We suspect that the sulfur atom of the thienyl group strongly stabilizes an initially formed silyl radical. This idea was supported both by