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Conjugated Microporous Networks on the Basis of 2,3,5,6-Tetraarylated Diketopyrrolo[3,4-c]pyrrole

✍ Scribed by Kai Zhang; Bernd Tieke; Filipe Vilela; Peter J. Skabara

Publisher: John Wiley and Sons
Year: 2011
Tongue: English
Weight: 433 KB
Volume: 32
Category: Article
ISSN: 1022-1336
DOI: 10.1002/marc.201100045

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✦ Synopsis

π-Conjugated microporous networks have been prepared from the tetraarylated diketopyrrolo[3,4-c]pyrrole unit as a tetrafunctional building block. The reactions are carried out using microwave-assisted Yamamoto or Sonogashira cross-coupling. Red insoluble powders are obtained, showing intense fluorescence. The polymer networks exhibit a high gas storage capability, with BET surface areas up to about 500 m^2^ · g^−1^.

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