## Abstract A novel NMP initiator functionalized with an alkyne group was synthesized and its polymerization behavior investigated. It was shown that the synthesized alkyne end‐functionalized polymers exhibit a linear relationship between calculated number‐averaged molecular weight and the experime
✦ LIBER ✦
Conjugated block copolymers via functionalized initiators and click chemistry
✍ Scribed by Smith, Kendall A.; Pickel, Deanna L.; Yager, Kevin; Kisslinger, Kim; Verduzco, Rafael
- Book ID
- 121836081
- Publisher
- John Wiley and Sons
- Year
- 2013
- Tongue
- English
- Weight
- 775 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0887-624X
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## Abstract Block copolymer synthesis via a combination of ATRP and RAFT using click chemistry is reported for the first time. A RAFT agent with a terminal propargyl group (PTTC) was synthesized and was used to polymerize butyl acrylate and gave quantitative monomer conversion. Azide‐terminated p(_