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‘Conjugate strategy’ of lanthanide porphyrinate with crown ether toward synergistic binding and chirality sensing of biological substrates

✍ Scribed by Hiroshi Tsukube; Masatoshi Wada; Satoshi Shinoda; Hitoshi Tamiaki

Book ID: 117619787
Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 327 KB
Volume: 323-324
Category: Article
ISSN: 0925-8388
DOI: 10.1016/s0925-8388(01)00994-x

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A novel conjugate receptor was designed to bind unprotected amino acids under acidic conditions and sense their chirality, in which 18-crown-6 ring was connected with carboxylic acid function via ferrocene spacer.