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Conjugate and Diels-Alder reactions of an activated allylidenedithiane

✍ Scribed by Danishefsky, Samuel.; McKee, Robert.; Singh, Rajendra K.


Book ID
127178525
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
272 KB
Volume
41
Category
Article
ISSN
0022-3263

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Generation and in situ Diels–Alder react
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Dienes readily undergo Diels-Alder reaction with CH 2 C(NO 2 )SO 2 Ph (2a), CH 2 C(NO 2 )CO 2 Et (2b), and CH 2 C(NO 2 )COPh (2c), all observed in situ by 1 H NMR. The cycloadducts of 2a undergo S RN 1 reactions.