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Conjugate Additions of Secondary Amines and Water to Allenyl Perfluoroalkyl Sulfones.

✍ Scribed by Xiao-Jin Wang; Yun Lin; Jin-Tao Liu


Book ID
101994518
Publisher
John Wiley and Sons
Year
2006
Weight
28 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract The dipolar cycloaddition reaction of allenyl perfluoroalkyl sulfones (**1**) to nitrones (**2**) was described. Unlike nonfluorine‐containing allenyl sulfones, **1** reacted readily with **2** in ether at room temperature and unusual zwitterionic cycloadducts (**3**) were obtained in g