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Conjugate Additions of Carbon Nucleophiles to Cyclopentadienones.

โœ Scribed by Anthony J. Pearson; Jin Bum Kim

Publisher
John Wiley and Sons
Year
2003
Weight
167 KB
Volume
34
Category
Article
ISSN
0931-7597

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The conjugate addition of benzylamine to three polyalkoxy a,benones derived from d-glyceraldehyde, d-erythrose, and d-mannose, whose carbonyls were flanked by the thiazole ring, proceeded with modest to good synselectivity. The resulting polyalkoxy bamino ketones were converted by ketalization into