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Conjugate addition of unactivated thiols to α,β-unsaturated ketones catalyzed by a bifunctional rhenium(V)–oxo complex

✍ Scribed by Allan Peng; Ross Rosenblatt; Kristine Nolin


Book ID
113930718
Publisher
Elsevier Science
Year
2012
Tongue
French
Weight
275 KB
Volume
53
Category
Article
ISSN
0040-4039

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The catalytic enantioselective conjugate addition reaction of fluorobis(phenylsulfonyl)methane to a,bunsaturated ketones promoted by chiral bifunctional organocatalysts is described. The treatment of fluorobis(phenylsulfonyl)methane to a,b-unsaturated ketones under mild reaction conditions afforded