✦ LIBER ✦

Conjugate addition of RMgX to mononitroarenes. Unequivocal evidence for a single-electron transfer mechanism

✍ Scribed by Bartoli, Giuseppe; Bosco, Marcella; Dal Pozzo, Renato; Ciminale, Francesco

Book ID: 126000459
Publisher: American Chemical Society
Year: 1982
Tongue: English
Weight: 394 KB
Volume: 47
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00147a045

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

New probes for electron-transfer process

New probes for electron-transfer processes. Evidence supporting the single-electron-transfer mechanism in additions of carbanions to dienones

✍ Liotta, Dennis; Saindane, Manohar; Waykole, Liladhar 📂 Article 📅 1983 🏛 American Chemical Society 🌐 English ⚖ 266 KB

Anti-markovnikov addition of nucleophile

Anti-markovnikov addition of nucleophiles to a non-conjugated olefin via single electron transfer photochemistry

✍ Paul G. Gassman; Kyle J. Bottorff 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 256 KB

Nucleophilic solvent has been added regiospecifically in an anti-Markovnikov manner to a simple non-conjugated olefin, l-methylcyclohexene, through single electron transfer induced photochemistry using the 1-cyanonaphthalene -biphenyl pair for achieving photooxidation. Although photoinduced additio

Hydrolysis of ethers of 2,4-dinitropheno

Hydrolysis of ethers of 2,4-dinitrophenol. No evidence for a single electron transfer mechanism

✍ de Vargas, Elba B.; Setti, Eduardo L.; Aimar, Mario L.; de Rossi, Rita H. 📂 Article 📅 1993 🏛 American Chemical Society 🌐 English ⚖ 457 KB

Kinetics and mechanism of the oxygenatio

Kinetics and mechanism of the oxygenation of potassium nitronates. Evidence for a single electron transfer (SET) mechanism

✍ Kaizer, József ;Durkó, Norbert ;Czaun, Miklós ;Speier, Gábor 📂 Article 📅 2006 🏛 Springer 🌐 English ⚖ 137 KB

Evidence for a single electron transfer

Evidence for a single electron transfer mechanism in the reduction of benzophenone with lithium alkoxides

✍ E.C. Ashby; J.N. Argyropoulos 📂 Article 📅 1986 🏛 Elsevier Science 🌐 French ⚖ 273 KB

The reduction of benzophenone by lithium alkoxides gives rise to benzophenone ketyl which disappears in a first-order fashion and whose first-order rate constant is approximately equal to the pseudo-first-order rate constant for the formation of the product, benzhydrol.

Evidence for a single electron transfer

Evidence for a single electron transfer mechanism in reactions of lithium diorganocuprates with organic halides

✍ E.C. Ashby; R.N. DePriest; A. Tuncay; Sushil Srivastava 📂 Article 📅 1982 🏛 Elsevier Science 🌐 French ⚖ 210 KB

It has been demonstrated by means of spectroscopic studies involving cyclizable alkyl halides that lithium dimethylcuprate can react with organic halides by a single electron transfer pathway. The reaction of lithium diorganocuprates (LiCuR2) with alkyl halides is of major synthetic imp0rtance.l