Chemoselectivity in the conjugate additi
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George Majetich; Ada M. Casares; D. Chapman; M. Behnke
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Article
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1983
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Elsevier Science
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French
โ 229 KB
The allylic carbanion species generated by treatment of allylsilane with fluoride ion undergoes highly chemoselective conjugate addition to a series of Michael acceptors for which alternative known allylation procedures proved less general. Conjugate addition of most nucleophilic reagents to an ~1