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Conjugate Addition In Phase Transfer Catalysis Conditions: Reactions of α Enones with Arylacetonitriles

✍ Scribed by Cossentini, Moncef; Seyden-penne, Jacqueline

Book ID
121183239
Publisher
Taylor and Francis Group
Year
1985
Tongue
English
Weight
267 KB
Volume
15
Category
Article
ISSN
0039-7911

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Conjugate Addition Reactions of α-Aminoa
Conjugate Addition Reactions of α-Aminoalkylcuprates with α,β-Enones and Enals
✍ R. Karl Dieter; Christopher W. Alexander; Lois E. Nice 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 218 KB

AbstractÐDeprotonation of Boc-protected amines with sec-BuLi or transmetallation of a-aminostannanes with n-BuLi affords a-aminoalkyllithium reagents which can be converted into a-aminoalkylcuprate reagents with CuCN or THF soluble CuCN´2LiCl. These reagents undergo conjugate addition reactions with