Conformers, Energetics, and Basicity of 2,2‘-Bipyridine
✍ Scribed by Howard, Sean T.
- Book ID
- 125433576
- Publisher
- American Chemical Society
- Year
- 1996
- Tongue
- English
- Weight
- 203 KB
- Volume
- 118
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The relative energies and dipolar properties of two conformers of 2,2V-bipyridine (1) were calculated using AM1 and ab initio methods. Dipole moments of 1 and pyridine in many organic solvents were determined. On this basis, the Gibbs energy DG (s) for the conformational s-transWs-cis equilibrium of
## Abstract Two bipyridine derivatives were synthesized and characterized, and their ability to act as sensors for carboxylates was evaluated by UV/Vis and fluorescence studies. The influence of the substituents of the thiourea groups on the stoichiometry of the resulting dicarboxylate complexes wa