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Conformers, Energetics, and Basicity of 2,2‘-Bipyridine

✍ Scribed by Howard, Sean T.


Book ID
125433576
Publisher
American Chemical Society
Year
1996
Tongue
English
Weight
203 KB
Volume
118
Category
Article
ISSN
0002-7863

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The relative energies and dipolar properties of two conformers of 2,2V-bipyridine (1) were calculated using AM1 and ab initio methods. Dipole moments of 1 and pyridine in many organic solvents were determined. On this basis, the Gibbs energy DG (s) for the conformational s-transWs-cis equilibrium of

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