Conformer dipole moment and syn-1,3-diaxial steric effect on the conformational equilibrium of the cis isomer of some 1,3-disubstituted cyclohexanes
β Scribed by Paulo R. de Oliveira; Roberto Rittner
- Publisher
- Elsevier Science
- Year
- 2005
- Tongue
- English
- Weight
- 86 KB
- Volume
- 743
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
NMR data, in CCl 4 , show that an increase in the concentration of cis-3-ethoxycyclohexanol (cis-3-ECH) shifts the conformational equilibrium from the ax-ax conformer (X ax-ax Z51% at 0.01 mol L K1 ), stabilized by an intramolecular hydrogen bond (IAHB), to the eq-eq conformer (X eq-eq Z67% at 0.40
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